A product analysis-based study on the mechanism of inflammable gas explosion suppression

To study the mechanism of the suppressing effect of Expanded Aluminium (EA) on the premixed gas explosion, premixed methane-air and propane-air gases were undergone explosion reaction in the presence of EA in a self-designed closed pipeline with the overpressures and the compositions, rates and sensitivities of products analyzed. The results showed that the 9.5% methane-air and 5% propane-air explosions produced peak pressures decreased by 79.3% and 65.6%, and residual methane and propane contents increased by 270% and 560% respectively than without EA. In addition, the results revealed that the explosions of propane in the presence of EA produced less methane and carbon oxides contents, but more ethylene and propylene contents. The simulation showed that H, O, and OH are the key factors affecting the rate of products. The product compositions, together with other parameters, suggested that EA decreased temperature, inhibited chain initiation and propagation reaction, but facilitated chain termination reaction by advancing and accelerating the gas phase and wall destruction reaction of radicals, especially collisions and concentration of key free radicals. This new research method based on the analysis of explosion products can be used for in-depth research into gas explosion features and shed light on the suppressing mechanism of EA in flammable gas explosion.     

Low‐concentration hydrogen peroxide decontamination for Bacillus spore contamination in buildings

Remediation and recovery efforts after a release of Bacillus anthracis (anthrax) spores may be difficult and costly. In addition, response and recovery technologies may be focused on critical resources, leaving the small business or homeowner without remediation options. This study evaluates the efficacy of relatively low levels of hydrogen peroxide vapor (HPV) delivered from off‐the‐shelf equipment for the inactivation of Bacillus spores within an indoor environment. Decontamination evaluations were conducted in a house using both Bacillus atrophaeus var. globigii (Bg; as surrogates for B. anthracis) inoculated on the carpet and galvanized metal as coupons and Geobacillus stearothermophilus (Gs) as biological indicators on steel. The total decontamination time ranged from 4 to 7 days. Using the longer exposure times, low concentrations of HPV (average levels below 20 parts per million) effectively inactivated Bg and Gs spores on the materials tested. The HPV was generated with commercial humidifiers and household‐strength hydrogen peroxide solutions. The presence of home furnishings did not have a significant impact on HPV efficacy. This simple, inexpensive, and effective decontamination method could have significant utility for remediation following a B. anthracis spore release, such as following a terrorist attack.     

Effects of release pressure on the transportation characteristics in pipeline and the diffusion behaviors in enclosure space of typical gas extinguishing agent

Reducing the release pressure of fire extinguishing systems can decrease potential safety hazards in large transport airplanes. To explore whether reducing the release pressure can achieve the release effect required by the airworthiness standards or not, the transportation characteristics in the pipeline and diffusion behaviors in the enclosure space of a typical fire extinguishing agent (Halon 1301) were investigated under five release pressures in the present study. The effects of the release pressure on the degree of superheat, injection duration, jet structure, and concentration distribution of Halon 1301 were analyzed. The results show that both of the degree of superheat and the injection duration decrease with an increase in the release pressure. The supplement of bubble expansion in the fire extinguishing agent can slow down the pressure decrease in the vessel. Both of the maximum and mean values of the pipeline differential pressure increase with an increase in release pressure. The maximum value of the jet angle decreases linearly with the increase in release pressure, and the jet deflects upward owing to the effects of buoyancy. The maximum concentration value decreases with an increase in the distance from the nozzle. The maximum concentration values in the near field from the nozzle increase with an increase in the release pressure. Under five release pressures, the concentration and holding time (duration above 6% volume concentration) of Halon 1301 on the centerline of the jet meet the requirements of airworthiness provisions.     

Evaluation of driver performance with a prototype cyber physical mid-block crossing advanced warning system

Introduction: Using connected vehicle technologies, pedestrian to vehicle (P2V) communication applications can be installed on smart devices allowing pedestrians to communicate with drivers by broadcasting discrete safety messages, received by drivers in-vehicle, as an alternative to expensive fixed-location physical safety infrastructure. Method: This study consists of designing, developing, and deploying an entirely cyber-physical P2V communication system within the cellular vehicle to everything (C-V2X) environment at a mid-block crosswalk to analyze drivers’ reactions to in-vehicle advanced warning messages, the impacts of the advanced warning messages on driver awareness, and drivers’ acceptance of this technology. Results: In testing human subjects with, and without, advanced warning messages upon approaching a mid-block crosswalk, driver reaction, acceptance, speed, eye tracking data, and demographic data were collected. Through an odds ratio comparison, it was found that drivers were at least 2.44 times more likely to stop for the pedestrian with the warning than without during the day, and at least 1.79 times more likely during the night. Furthermore, through binary logistic regression analysis, it was found that driver age, time of the day, and the presence of the advanced warning message all had strong, significant impacts with a confidence value of at least 98% (p < 0.02) on the rate at which drivers stopped for the pedestrian. Conclusions: The results from this study indicate that the advanced warning message sent within the C-V2X had a strong, positive impact on driver behavior and understanding of pedestrian intent. Practical Applications: Pedestrian crashes and fatality rates at mid-block crossings continue to increase over the years. Connected vehicle technology utilizing smart devices can be used as a means for communications between pedestrians and drivers to deliver safety messages. State and local city planners should consider geofencing designated mid-block crossings at which this technology operates to increase pedestrian safety and driver awareness.     

Alcohol-impaired motorcyclists versus car drivers: A comparison of crash involvement and legal consequence from adjudication data

Introduction: Driving under the influence (DUI) increases the probability of motor-vehicle collisions, especially for motorcycles with less protections. This study aimed to identify commonalities and differences between criminally DUI offenses (i.e., with a blood alcohol concentration (BAC) of 80 mg/dL or higher) committed by motorcyclists and car drivers. Methods: A total of 10,457 motorcycle DUIs and 8,402 car DUIs were compared using a series of logistic regression models, using data extracted from the documents of adjudication decisions by the courts of Jiangsu, China. Results: The results revealed that offenders from the high-BAC group (i.e., 200 mg/dL or higher) accounted for more than 20% of the total DUI offenses, and were more likely to be involved in a crash and punished with a longer detention. Motorcyclists had a higher likelihood of crash involvement, and were also more likely to be responsible for single-vehicle crashes associated with higher odds of injury sustained, compared to alcohol-impaired car drivers. In the verdict, motorcycle offenders were more likely to receive a less severe penalty. Conclusions: Interventions are clearly required to focus on reducing in the high-BAC group of offenders. For alcohol-impaired motorcyclists, their risks of crash and injury against BAC climb more steeply than the risks for car drivers. The factors including frequent occurrences, uncertainty of detection, and short-term sentences may weaken the deterrence effect of the criminalization of motorcycle DUI. Practical Applications: The traffic-related adjudication data support traffic safety analysis. Strategies such as combating motorcycle violations (e.g., unlicensed operators or driving unsafe vehicles), undertaking education and awareness campaigns, are expected for DUI prevention.     

The acceptance of personal protective equipment among Hong Kong construction workers: An integration of technology acceptance model and theory of planned behavior with risk perception and safety climate

Introduction: The phenomenon that construction workers do not use personal protective equipment (PPE) is a major reason for the high occurrence frequency of accidents in the construction industry. However, little efforts have been made to quantitatively examine the factors influencing construction workers’ acceptance of PPE. Method: In the current study, a PPE acceptance model for construction workers (PAMCW) was proposed to address the noted need. The PAMCW incorporates the technology acceptance model, theory of planned behavior, risk perception, and safety climate for explaining construction worker acceptance of PPE. 413 construction workers participated in this study to fill out a structured questionnaire. The PAMCW was analyzed using structural equation modeling. Results: Results provide evidence of the applicability of the technology acceptance model and theory of planned behavior to the PPE acceptance among construction workers. The positive influence of safety climate and risk perception-severity on attitude toward using PPE was significant. Safety climate positively influences perceived usefulness. Risk perception-worry and unsafe was found to positively affect intention to use PPE. Practical Applications: Practical suggestions for increasing construction workers’ use of PPE are also discussed.     

Inhibiting effects by Fe2O3 on combustion and explosion characteristics of ABS resin

The global increase in the use of, and reliance on, plastics has prompted the demand for acrylonitrile-butadiene-styrene (ABS) resin in various fields. With this increased requirement, numerous failures have occurred in the ABS process. Those incidents, resulting from electrostatic discharge, powder accumulation, heat accumulation, construction sparks, and plant fires, have caused dust fire and explosions.In this study, the ABS resin was gleaned from the site and tested for its explosion parameters, including minimum ignition temperature of dust cloud (MIT_C), minimum ignition energy (MIE), and minimum explosion concentration (MEC). To improve loss prevention in the manufacturing process, ferric oxide (Fe₂O₃) as an inert additive was added in the ABS powder. According to the MIE test, Fe₂O₃ has an apparent inhibiting effect on dust explosion for the ABS dust. With the proportion of Fe₂O₃ increased from 25 to 50 mass% in ABS, the MIE increased from 67 to 540 mJ. The explosion tests via 20-L apparatus indicated that Fe₂O₃ mixed with ABS could not increase the MEC significantly. However, the explosion pressure dropped by increasing in the ratio of Fe₂O₃ in ABS. This inerting strategy of ABS was deemed to substantially lessen the probability and severity of fire and explosion.     

Assessment of the effect of technical and management characteristics on the frequency of release from piping: An application to a gas storage facility

The assessment of the frequencies of release from piping due to losses of containment is an essential step in the preparing Safety Reports, drawn up as required by the so-called “Seveso” Directive. These are usually calculated starting from the frequencies of random rupture included in international databases and are not plant-specific, furthermore, the quantification of the effect of the safety management system of the facility is not easy. A simple and flexible approach quantifying technical and management characteristics of the plant has been proposed by Milazzo and co-workers in 2010; it is based on the modification of the frequency taken from literature, through the use of the percentages of failure causes actually possible in that plant, and the judgment about their management. The data about the failure causes are taken from the literature and modified by using corrective factors to adapt them to the industrial context. To make possible the application of the method to a large number of major-hazard industry types, some aspects of the approach needed to be improved; these have been identified during a development project coordinated by RINA Consulting, on behalf of Saipem, with the collaboration of the University of Messina. The improvement of the approach focused on two main points, the development of a method to calculate the corrective factors for the failure causes associated with corrosion and erosion phenomena and the strengthening of the methodology for the formulation of the judgment about the safety management. This paper illustrates the fully improved method, as well as an application to a typical gas storage plant.     

高效复合菌在木薯酒精废液处理中的应用研究

对酒精废液生物处理反应器内颗粒污泥中的微生物进行分离纯化.分离出的8株高效优势菌,初步鉴定结果:1号为皮杆菌属;2号为棒杆菌属;3号、4号为微小杆菌属;5号为乳杆菌属;6号为纤维单胞菌属;7号为丙酸杆菌属;8号为红长命菌属.对8种纯化后的菌株进行混合培养,确定了复合菌群生长最佳培养温度为37℃,最适pH值为6.8.在处理过程中投加适量葡萄糖、硝酸铵和微量元素能够提高复合菌群的处理效果.最佳添加量为:葡萄糖0.5g/L,硝酸铵1g/L,Fe2 5mg/L和Ca2 25mg/L.在日处理量100 m3的UASB生物反应器中投加该复合菌群后,木薯酒精废液的COD去除率明显提高,达到90%以上.处理系统运行稳定.     

长三角和珠三角土壤中汞的化学形态、转化和吸附特性

为了解长江三角洲和珠江三角洲农业土壤中汞的积累可能产生的环境影响,选择10个代表性农业土壤样品,研究了土壤中汞的化学形态、积累过程中形态的转化及吸附-解吸行为.研究表明,当无外源汞加入时,长江三角洲和珠江三角洲农业土壤中,汞主要以稳定的残余态形式存在.但随着汞加入量的增加,土壤中可交换态汞显著增加,增加程度与土壤性质有关.土壤pH是影响土壤汞有效性最重要的因素,其对土壤汞的吸附、解吸、形态转化和存在形态均有很大影响.土壤酸化可促进土壤汞的释放,加剧对环境的危害,防治土壤酸化也可有效降低土壤中汞对环境的危害.